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Carboxylic Acids The idea of a gaseous fluxing agent has much merit. It could be inexpensive, eliminate postsolder cleaning, and leave no residue to impede inspection or test. Without residues, the prospect of corrosion would be minimized. Carboxylic acids in gaseous phase have been demonstrated to be useful in this regard, but it has yet to undergo large-scale testing in a manufacturing environment. Of the carboxylic acids, formic and acetic have received some attention as fluxing agents. They are very simple materials, weak organic acids that decompose to water and carbon dioxide at temperatures above 160 C.18 Acetic, in its dilute form, is vinegar. Both formic and acetic are widely used industrially and are inexpensive reagents. H. J. Hartmann19, 20 has shown that as formic decomposes, it is a good reducing agent for oxides of solder. The process produces meta-stable tin formate, which further decomposes, yielding elemental tin, water, and carbon dioxide.Acetic acid follows a similar reaction and decomposition cycle, forming meta-stable tin acetate and ultimately elemental tin. Especially attractive is the fact that there is no flux residue on the circuit board after the gaseous carboxylic acid reactive soldering process. R. Iman et al.21 have demonstrated formic and acetic to be especially effective for fluxing in the wave-soldering process in conjunction with a light application of adipic acid, a common food preservative and also a known fluxing agent. However, a water rinse was required to remove the adipic residue. Work by G. Disbon and S. M. Bobbio22 and K. Pickering, et al.23 has demonstrated that a plasma can be used to strip oxides from circuit boards and components, and, if they are maintained in an inert environment, they can be soldered without the use of additional liquid fluxing agents. In these schemes, the plasma serves as the oxide-stripping flux.

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the hole formedThis happens because an undercured resin system, and the resulting lower than normal Tg, will result in excessive softening of the resin when it is subjected to the heat generated during the drilling process If this smeared resin is not completely removed, it can prevent electrical connection when the hole is plated with copper In addition, finished circuits in which the resin system is not fully cured can exhibit greater amounts of Z-axis thermal expansionThis Tg1 Tg2 adversely affects circuit board reliability due to Temperature the increased stress on the plated through holes as the circuit expands FIGURE 62 Measuring the degree of cure by Because increased cross-linking will require measuring Tg values.

(Contd )

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In addition to the shift register method of expanding the I/O capacity of an AVR processor, there exists another method to expand I/O capacity. The idea is to use IIC bus-based I/O expander ICs. Manufacturers have perceived the need for increasing the I/O and have designed chips for the purpose. Philips, who is the developer of the IIC bus has designed

greater amounts of energy (heat) to weaken the bonds in the molecular structure of the resin system, measurements of Tg can be used to determine the degree of cure of the resin system For example, a measure of the degree of cure can be obtained by performing two thermal analyses on the same sample After the first analysis, the sample is subjected to a thermal cycle designed to promote any additional cross-linking available within the resin system, and then a second thermal analysis is performed The degree of cure is measured by comparing the difference in measured Tg between the two analyses (see Fig 62) If the material is fully cured, the difference between Tg2 and Tg1 will be very small, typically within a few degrees Celsius.

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Negative differences in these measured values or negative delta Tg values where Tg1 is greater than Tg2 are also indicative of full cure However, great care must be exercised when using these methods to assess degree of cure An understanding of the resin system is important because not all resins will behave the same way when performing sequential tests such as this The degree of cure for some advanced resin systems is not easily assessed by these techniques In addition, sample preparation methods, particularly sample drying prior to testing, can also influence results 6313 Advantages and Disadvantages of High Tg Values Implicit in many discussions of Tg is the assumption that higher values of Tg are always betterThis is not always the case.

While it is certainly true that higher values of Tg will delay the onset of high rates of thermal expansion for a given resin system, total expansion can differ from material to material A material with a lower Tg could exhibit less total expansion than a material with a higher Tg, due to differing resin CTE values or by incorporating fillers into the resin system that lower the CTE of the composite material This is illustrated in Fig 63 Material C exhibits a higher Tg than material A, but material C exhibits more total thermal expansion because its CTE value above Tg is much higher On the other hand, with the C same CTE values above and below the Tg, the higher-Tg material B exhibits less total thermal expansion than material A.

Finally, although the Tg values are the same, material B exhibits less total expansion than material A C due to a lower CTE value above Tg This will be discussed further in Chap 10 in the B context of the impact of lead-free assembly temperatures on base materials There are other considerations as well Most notably, many standard 140 C Tg FR-4 materials exhibit higher decomposition temTemperature peratures, Td s, than the standard 170 C Tg FR-4sTd is an important property for lead-free FIGURE 63 Tg versus thermal expansion..

Table 710 (Contd)

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